ADMET polymerization of biobased monomers deriving from syringaresinol

Louis Hollande; Abdus Samad Jaufurally; Paul-Henri Ducrot; Florent Allais

ADMET polymerization of biobased monomers deriving from syringaresinol

Louis Hollande Abdus Samad Jaufurally Paul-Henri Ducrot ¹ Florent Allais ^{2, 3}

2 GMPA - Génie et Microbiologie des Procédés Alimentaires

3 ABI - Agro-Biotechnologies Industrielles

Abstract : Renewable α,ω-dienes have been prepared from syringaresinol, a naturally occurring bisphenol deriving from sinapyl alcohol, and further studied as monomers in ADMET polymerizations. Polymerization was optimized according to catalyst loading and reaction conditions (in mass vs. in solvent), and led to polymers with molecular weight up to 14.1 kDa. Thermal analyses of these new polymers showed excellent thermal stabilities (257–360 °C) and tunable Tg (18–70 °C) depending on the structure of the starting α,ω-diene monomer.

Document type :

Journal articles

Domain :

Life Sciences [q-bio]

Complete list of metadatas

https://hal-agroparistech.archives-ouvertes.fr/hal-01598621
Contributor : Eva Legras <>
Submitted on : Friday, September 29, 2017 - 4:57:21 PM
Last modification on : Wednesday, July 3, 2019 - 11:22:09 AM

ADMET polymerization of biobased monomers deriving from syringaresinol

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ADMET polymerization of biobased monomers deriving from syringaresinol

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