ADMET polymerization of biobased monomers deriving from syringaresinol

Abstract : Renewable α,ω-dienes have been prepared from syringaresinol, a naturally occurring bisphenol deriving from sinapyl alcohol, and further studied as monomers in ADMET polymerizations. Polymerization was optimized according to catalyst loading and reaction conditions (in mass vs. in solvent), and led to polymers with molecular weight up to 14.1 kDa. Thermal analyses of these new polymers showed excellent thermal stabilities (257–360 °C) and tunable Tg (18–70 °C) depending on the structure of the starting α,ω-diene monomer.
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Article dans une revue
RCS advances, RSC Publishing, 2016, 6 (50), pp.44297 - 44304. 〈10.1039/C6RA06348A〉
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https://hal-agroparistech.archives-ouvertes.fr/hal-01598621
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Soumis le : vendredi 29 septembre 2017 - 16:57:21
Dernière modification le : samedi 30 septembre 2017 - 01:14:56

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Louis Hollande, Abdus Samad Jaufurally, Paul-Henri Ducrot, Florent Allais. ADMET polymerization of biobased monomers deriving from syringaresinol. RCS advances, RSC Publishing, 2016, 6 (50), pp.44297 - 44304. 〈10.1039/C6RA06348A〉. 〈hal-01598621〉

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